468

1 DIVISION OF ADMINISTRATIVE HEARINGS

DEPARTMENT OF ADMINISTRATION, STATE OF FLORIDA

2

3 SUGAR CANE GROWERS COOPERATIVE )

OF FLORIDA; ROTH FARMS, INC., and )

4 WEDGWORTH FARMS, INC., )

Petitioners, ) DOAH Case No. 92-3038

5 v. )

SOUTH FLORIDA WATER MANAGEMENT )

6 DISTRICT, an agency of the State )

of Florida; et al., )

7 Respondents. )

- - - - - - - - - - - - - - - - - - x

8 FLORIDA SUGAR CANE LEAGUE, INC.; )

UNITED STATES SUGAR CORPORATION; )

9 and NEW HOPE SOUTH, INC., )

Petitioners, )

10 v. ) DOAH Case No. 92-3039

SOUTH FLORIDA WATER MANAGEMENT )

11 DISTRICT, an agency of the State )

of Florida; et al., )

12 Respondents. )

- - - - - - - - - - - - - - - - - - x

13 FLORIDA FRUIT AND VEGETABLE )

ASSOCIATION; LEWIS POPE FARMS; )

14 W.E. SCHLECHTER & SONS, INC., )

and HUNDLEY FARMS, INC., )

15 Petitioners, )

v. ) DOAH Case No. 92-3040

16 SOUTH FLORIDA WATER MANAGEMENT )

DISTRICT, an agency of the State )

17 of Florida; et al., )

Respondents. )

18 - - - - - - - - - - - - - - - - - - x

100 S.E. 2nd Street

19 Miami, Florida 33131

Wednesday, February 9, 1994

20 8:30 a.m. - 4:00 p.m.

21 DEPOSITION OF RONALD D. JONES

22 Taken before BRIAN GARY BERKOWITZ, Shorthand

Reporter and Notary Public in and for the State of

23 Florida at Large, pursuant to Notice of Taking

Deposition filed in the above cause.

24 - - - - - - -

469

1 APPEARANCES

2 ON BEHALF OF THE PETITIONERS SUGAR CANE GROWERS

COOPERATIVE OF FLORIDA, ROTH FARMS, INC. AND

3 WEDGWORTH FARMS, INC.

4 HOPPING BOYD GREEN & SAMS

123 South Calhoun Street

5 Tallahassee, Florida 32314

BY: GARY P. SAMS, ESQ.

6 WILLIAM H. GREEN, ESQ.

7 ON BEHALF OF THE PETITIONERS FLORIDA SUGAR CANE LEAGUE,

INC., UNITED STATES SUGAR CORP., AND NEW HOPE SOUTH, INC.

8

EARL BLANK KAVANAUGH & STOTTS, P.A.

9 One Biscayne Tower - Suite 3636

Two South Biscayne Boulevard

10 Miami, Florida 33131

BY: WILLIAM L. HYDE, ESQ.

11 ROBERT H. BLANK, ESQ.

12 ON BEHALF OF THE RESPONDENT SOUTH FLORIDA

WATER MANAGEMENT DISTRICT

13

STANLEY J. NIEGO, ESQ.

14 South Florida Water Management District

3301 Gun Club Road

15 West Palm Beach, Florida 33406

16 ON BEHALF OF THE RESPONDENT-INTERVENOR

UNITED STATES OF AMERICA

17

SUZAN HILL PONZOLI, ESQ.

18 Assistant United States Attorney

99 N. E. 4th Street

19 Miami, Florida 33132

20 ALSO PRESENT:

B. J. PRESLEY

21 TRUMAN E. DUNCAN

JOHN A. DAVIS

22

- - -

470

1 INDEX

2 Witness Direct Cross Redirect Recross

3 RONALD D. JONES

4 By Mr. Hyde 471

5 By Mr. Sams 503

6

7 JONES EXHIBITS

8 Exhibit 60 Documents with Bates No. 8626 486

9 Exhibit 61 Documents with Bates No. 9462 492

10 Exhibit 62 Group of documents 503

11 Exhibit 63 Results produced by Battelle 542

12 Exhibit 64 Documents containing Appendix C 545

13 Exhibit 65 Documents with Bates No. 8058 556

14 Exhibit 66 Documents beginning

15 "Environmental Parameters" 578

16 Exhibit 67 Barkay study 589

17 Exhibit 68 Request to Dr. Soukup 594

18 Exhibit 69 Report by Rathi Kavanaugh 597

19 Exhibit 70 Report re Dr. Barkay 601

20 Exhibit 71 Contract 605

21 Exhibit 72 Portion of a document 606

22 Exhibit 73 Letter from Mr. Finger 608

23 Exhibit 74 Document with blue cover 611

24 - - -

471

1 Thereupon --

2 RONALD D. JONES

3 was called as a witness and, having been first duly

4 sworn, was examined and testified as follows:

5 DIRECT EXAMINATION

6 BY MR. HYDE:

7 Q. Dr. Jones, just to remind you once again,

8 that you are still under oath.

9 Dr. Jones, when we left off the other day,

10 you had committed to examining some of your files, at

11 least, and making some determinations as to some data

12 that we had been discussing, at least in a tabular

13 form, and I think it was Jones Exhibit No. 16,

14 yesterday.

15 Did you in fact go back and examine your

16 files?

17 A. I did.

18 Q. What did you do?

19 A. I went back, pulled the data from the --

20 examined the appropriate folder, file folder, and

21 concur with your description of this data, as

22 representing analysis of samples collected along with

23 the sugar cane, with their exact entry and access into

24 Everglades National Park.

25 Q. Just to be clear, so these were the samples

472

1 that you took while you were on that entry and access?

2 A. These were the samples that I took after

3 examining my notes, field notes. I am not certain that

4 I collected all of the soil samples. Su Jewell may

5 have collected a couple of the soil samples.

6 Q. Is Su Jewell someone who works with you?

7 A. She works with Loxahatchee National Wildlife

8 Refuge.

9 Q. Was she taking the samples under your

10 supervision?

11 A. At the time, if she would have collected any

12 of the samples, then she would not have been under my

13 supervision, because I would not have been along.

14 Q. You mean you wouldn't have been along on the

15 helicopter?

16 A. With her. We went a number of days together.

17 On the days she would have collected those samples, she

18 would have done them on her own.

19 Q. Did you bring that file folder with you?

20 A. I brought the material that it contained.

21 Q. Could we take a moment and examine that?

22 A. Sure.

23 MR. HYDE: Off the record.

24 (Discussion off the record.)

25 MR. HYDE: We would like -- it appears to be

473

1 DRJ Bates Nos. 00009462 through 9463, and then

2 8601 through 8665. That, apparently, is the

3 extent of it.

4 The other document is a notebook, I take it,

5 of field notes, for lack of a better term, and it

6 is DRJ Bates number 00009281 through 9284, and

7 there's also a small map of South Florida

8 included, which is Bates number 9285, DRJ.

9 MS. PONZOLI: As you can see, Mr. Hyde, all

10 of these pages are Bates numbered and have been

11 turned over to you previously.

12 Dr. Jones is providing a courtesy second

13 copy.

14 MR. HYDE: We appreciate that. It's nice to

15 have them in one fell swoop, so they can all be

16 together for future analysis.

17 MR. HYDE: Let's take a break here and make

18 copies.

19 (Thereupon, a brief recess was taken,

20 after which the following proceedings

21 were had:)

22 BY MR. HYDE:

23 Q. Dr. Jones, concerning your Loxahatchee

24 related sampling, could you please describe in a fairly

25 summary fashion, your part in the analysis of the

474

1 samples taken during the League's sampling in the

2 Refuge?

3 A. Samples were transported to my laboratory, by

4 Refuge staff, and we then analyzed them in the normal

5 manner that we would for either water or soil samples.

6 Q. Did you do the sampling yourself in the

7 field?

8 A. No.

9 Q. Who did that for you?

10 A. Refuge staff.

11 Q. Could you be more specific? Do you know who

12 those individuals were?

13 A. I know that Su Jewell participated in that

14 sampling. I do not -- and I know there were others. I

15 don't know who they would be.

16 Q. How did you handle the samples once they were

17 delivered to your lab?

18 A. In the customary manner. We generally would

19 place them in the refrigerators or freezers that we use

20 for storing the samples, if we were not going to be

21 doing the analysis immediately.

22 Generally, the samples were analyzed as

23 rapidly as they could be, so in some cases they would

24 not have received any kind of refrigeration or

25 freezing, because we would have started the analytical

475

1 procedures at the time of sample receipt.

2 Q. How long did it take for the final ones, to

3 get them completely done?

4 I didn't say that quite right. You just said

5 that you tried to do that as quickly as possible. How

6 long did it take to do the whole batch?

7 A. There are certain steps in the process, which

8 you can hold the samples indefinitely. For instance,

9 for soils, once they're dried and ground, there's no

10 appreciable changes in the phosphorus content, so that

11 time would vary.

12 It could be as rapidly as one to two days, or

13 it could have extended for a considerable period of

14 time, depending upon how busy we were in the

15 laboratory.

16 Q. These were water samples, weren't they?

17 A. They're water and soil samples.

18 Q. They were. Okay.

19 Dr. Jones, do your lab notes reflect how long

20 the water samples were held?

21 A. The analysis date would be on the file, along

22 with the date of sample collection. So, you could

23 determine that.

24 We would -- these were total phosphorus

25 samples, so, therefore, there is no -- it'S not

476

1 critical as to when -- what length of time you hold the

2 samples.

3 Q. Did you do any pre-treatment of the samples?

4 A. No.

5 Q. Did you do anything to remove any detritus

6 suspended solids from the samples? We're speaking here

7 about the water samples, obviously.

8 A. I understand. These samples were not

9 collected by myself or my staff, and therefore, some of

10 the samples contained material that they should not

11 have.

12 In one case there was a small fish in one of

13 the bottles. We did not analyze the fish. We did,

14 however, make a note that that sample was suspect.

15 Q. Were the exact same procedures used on all of

16 these water samples?

17 A. Yes.

18 Q. How many bottles were you given for each of

19 the sampling stations?

20 A. I believe two. I'm not -- not certain at the

21 moment. Our general procedure is to collect duplicate

22 samples at every location.

23 Q. Were the bottles treated differently?

24 A. The individual -- no. They were treated in

25 the same manner.

477

1 Q. You did analyze each bottle. Is that

2 correct?

3 A. Yes.

4 Q. Did you turn over total phosphorus values for

5 each of the samples?

6 A. I turned over the value for -- for that

7 particular station, those particular sites.

8 Q. Do you have the replicate values for those

9 particular stations?

10 A. Machine output might still be in the folders.

11 Generally, we don't -- we don't produce that. I

12 believe it's the same mechanism which the League has

13 turned their data over to us. I don't know if that's

14 true for sure.

15 Q. I've been advised that the League did provide

16 replicate values. So, if it's possible, we would like

17 to obtain copies of the replicate values as well. I

18 presume that wouldn't be too difficult an operation.

19 Would it?

20 A. They're going to be buried amongst all the

21 other analysis we do for Florida Bay, White Water Bay,

22 the regular output, other students' projects and things

23 like that. But I think there's -- you know, we

24 probably have computer forms from the output of the

25 machine that we could produce.

478

1 Q. We would like to get a copy of them.

2 A. Okay.

3 MS. PONZOLI: We would, of course, ascertain

4 that you did give us the replicates. I take your

5 word that you did.

6 MR. HYDE: I was advised by Dr. Davis that we

7 did.

8 MS. PONZOLI: I have no knowledge whether you

9 did or didn't.

10 THE WITNESS: From my standpoint, I did not

11 see any machine output from them.

12 MS. PONZOLI: It would be reciprocal. If, in

13 fact, we did not receive your machine output with

14 the replicates, then you would provide that to us?

15 MR. HYDE: Certainly.

16 We're talking about replicate values here as

17 opposed to machine output. We don't need Dr.

18 Jones' machine output. We just want the replicate

19 values.

20 THE WITNESS: That would require me to go

21 back to all of the machine output, and pull the

22 samples and tabulate them.

23 MR. HYDE: Okay.

24 THE WITNESS: You're not going to receive

25 that in the next couple of weeks.

479

1 MS. PONZOLI: In other words, this is a long

2 task, is what you are telling Mr. Hyde?

3 THE WITNESS: Yes. It can take me several

4 weeks to do this.

5 MS. PONZOLI: Of straight work.

6 THE WITNESS: Of going digging through the

7 thousands of pages of material we have of machine

8 output, yes.

9 MS. PONZOLI: Mr. Hyde, I'm going to attempt

10 to reconstruct what you did in fact turn over to

11 us, and if we in fact matched what you were

12 turning over, and it's going to take Dr. Jones two

13 straight weeks of personal work to bring this up,

14 then there may be a problem in producing it.

15 We will make an honest effort to produce it,

16 if it can be done easier, and if you have done

17 that in the past for us.

18 If not, then I think we will have to address

19 the problem again.

20 MR. HYDE: Okay. Let's just move on at this

21 point, but hopefully, we can resolve this fairly

22 easily.

23 BY MR. HYDE:

24 Q. Were any parameters other than total

25 phosphorus, measured in these samples?

480

1 A. No.

2 Q. Was the information that you turned over, a

3 reflection of one of the samples, or was it an average

4 of the two samples?

5 A. It would be an average of whatever samples

6 were collected. This data was only analyzed for the

7 purpose of seeing whether the League's data was

8 reasonable. We didn't have any -- I have not looked at

9 these data since the tabulation of this table.

10 Q. Are the field notes that are presently being

11 copied, the field notes of that particular expedition?

12 A. They are. Well, I'm -- we have been talking

13 about Loxahatchee.

14 Q. Correct.

15 A. Then, the answer for that would be no.

16 Q. Because you weren't the person that conducted

17 the field sampling efforts?

18 A. That's correct. The field notes may be

19 attached to the back of that entire file. They would

20 be Su Jewell's notes, and I'm almost certain they were

21 attached to the back of those.

22 Q. Have you, yourself, collected any samples at

23 any of the Refuge 16 sampling stations that are

24 identified?

25 A. I have not, under this scenario. In other

481

1 words, I've been in the Refuge many times, and I may

2 have been at one of those sites, and collected a

3 sample. I would not have been able to identify it as

4 one of the 16 stations.

5 Q. So, you have visited one or more of these 16

6 stations?

7 A. I've been over a large geographic area of the

8 Refuge. I'm just saying that I may very well have

9 something that fits latitude and longitude. I wouldn't

10 have any idea whether that represented one of the 16

11 stations or not.

12 Q. So, you have analyzed other samples than the

13 samples that were collected by Ms. Jewell at this

14 League sampling effort?

15 A. No.

16 Q. Were you consulted by Ms. Jewell, or whoever

17 collected these samples, as to the proper method for

18 collection?

19 A. I spent a day at the Refuge, instructing Ms.

20 Jewell on what I would consider to be appropriate

21 methodology for collecting these particular samples.

22 I'm not certain that she collected the

23 samples. In some cases, for instance, on my entry into

24 the EAA, the samples that I collected, for instance,

25 were for the League, to my knowledge. In some cases,

482

1 were collected for Dr. Davis. He would toss me the

2 bottle and I would fill it up, and I don't know if that

3 was -- as not being in the Refuge, I don't know what

4 manner those samples were collected. They may have

5 been collected by Refuge staff, and they may not have

6 been, now that I think of it.

7 Q. Have you compared the data collected in these

8 samples, with the data collected by the League's

9 consultants and the Water Management District?

10 A. For the Refuge?

11 Q. Yes.

12 A. Briefly.

13 Q. How well do you think they agree with each

14 other? That's not a good way of putting it.

15 Are these data results consistent with each

16 other?

17 A. There are certain consistencies. There would

18 appear to be some inconsistencies, and those have not

19 been resolved.

20 I have given the data to Refuge staff, and I

21 am assuming that they are -- will be making those

22 interpretations, perhaps consulting with me, as to my

23 opinions on that, but that has not taken place yet.

24 Q. Do you have any explanation as to these

25 apparent differences between the data samples?

483

1 A. Without -- I haven't gone into enough

2 specifics to see whether there are really differences.

3 I just say there appear to be some differences. There

4 appear to be a lot of consistency. We have not made

5 any kind of detailed discussion, so I don't have any

6 opinion at this moment on that.

7 Q. The next question concerns any sampling

8 efforts you might have done in the Refuge, since

9 January of 1991.

10 Have you done any sampling there, other than

11 that which Ms. Jewell apparently did, on the League's

12 entry and access sampling effort?

13 A. I may have, but I don't believe so. That's a

14 fairly long period of time, and I'm having trouble

15 remembering '91 and '92 as to, you know, exactly what

16 locations I sampled in the EPA.

17 Q. Dr. Jones, I'd like to ask you a few

18 questions about several of the specific documents that

19 are in that batch that are currently being copied. The

20 first one is Bates number DRJ 8630. Maybe I can just

21 provide it to you.

22 What I'm looking at here is in the final

23 column. Under "TP concentration," there are several

24 values that were typewritten in, and then apparently

25 stricken through, and some changes were made to them.

484

1 Can you explain what those changes are?

2 MS. PONZOLI: This document is among the ones

3 that you are going to attach as a composite

4 exhibit, as soon as the court reporter brings the

5 copies back. Is that accurate?

6 MR. HYDE: Yes, it is.

7 MR. BLANK: We believe so.

8 MS. PONZOLI: Why don't we make it an exhibit

9 now, Mr. Blank?

10 THE WITNESS: I don't know why it has two

11 sides. None of the stuff I had, had two sides.

12 MS. PONZOLI: We may have copied it that way.

13 MR. BLANK: It was my understanding that the

14 file folder he turned over, was a part entry and

15 access file folder.

16 Did it have more at Loxahatchee, also?

17 MS. PONZOLI: I don't know, but it's clear

18 from at least the way we keep our records, the

19 fact that those arrived Bates stamped, they were

20 all turned over to you.

21 You would have taken them, because we only

22 Bates stamped what you took, when we did that

23 supplemental production. You took those

24 somewhere.

25 MR. BLANK: These are our copies that we have

485

1 right now.

2 MS. PONZOLI: I mean the ones that are being

3 copied presently by the court reporter, were also

4 taken.

5 MR. BLANK: That may be. Some of them were

6 probably illegible, is why we needed other copies.

7 The field note copies certainly were, what we got.

8 MS. PONZOLI: I can't be responsible for the

9 copier.

10 MR. HYDE: We're not blaming you for that.

11 Can we take a brief break here and you can

12 check on the status of that copying effort?

13 (Thereupon, a brief recess was taken,

14 after which the following proceedings

15 were had:)

16 BY MR. HYDE:

17 Q. Dr. Jones, I'd like you to turn your

18 attention to the Loxahatchee data, specifically 8630.

19 MR. NIEGO: Are we going to mark these?

20 MR. HYDE: Yes. Why don't we just say this

21 is composite Exhibit 60?

22 MS. PONZOLI: Are you including the field

23 notes, or are they separate?

24 MR. HYDE: We will do them separately. I

25 think they're already in the record, anyway.

486

1 MR. SAMS: What number are you doing, Bill?

2 MR. HYDE: Let's just mark as Exhibit 60, the

3 Loxahatchee data, beginning with Bates number

4 8626, through 8663. Excuse me, 665. 8665.

5 (The document referred to was thereupon

6 marked Jones Exhibit 60 for Identification.)

7 A. Yes, sir. What page?

8 Q. 8630.

9 Can you explain to me, Dr. Jones --

10 A. One moment, please.

11 Q. I'm sorry. It should be about four pages

12 back.

13 A. I'm just about there.

14 Q. As I was saying earlier, in the far right

15 column, under "TP concentration," there are some

16 handwritten values that are set forth in line one and

17 line five.

18 Can you explain to me what those are supposed

19 to represent?

20 A. Yes. It says, "Greater than 60 parts per

21 billion."

22 Q. Why did you strike out these actual values

23 that were set forth in line one? For example, 941.47.

24 A. When I examined this data, as required, I was

25 being responsible for the numbers that are here before

487

1 turning it over to Loxahatchee. You see a number like

2 941 or 947 or anything greater than -- I think probably

3 anything greater than, under -- in this circumstance,

4 right around 90 parts per billion, it indicates that --

5 a machine overload, that there was an air bubble or

6 something in that particular series of samples, so it

7 went off scale, and since these have not been replaced

8 with anything else, apparently, I was out somewhere at

9 the time, and these samples were no longer recoverable.

10 In other words, we couldn't go back into the

11 refrigerator and pull out additional samples to rerun

12 these samples.

13 So, the only thing I could say is, it's

14 greater than 60.

15 Q. Why did you choose 60?

16 A. That's the -- let's see. This is total

17 phosphorus in water. Probably close to the value of

18 the -- the high standard, which was two micromolar. It

19 doesn't mean you cannot measure values higher than

20 that, but I didn't ascertain what full scale was.

21 Probably it was greater than, you know, 89.18 or 89 --

22 something like that. I don't know what that value

23 would be.

24 Q. Also on that same page, under the first

25 column, H2O bottle ID, there is a 4 and 4-F, as well as

488

1 an 8 and 8-F.

2 Are these replicate values?

3 A. I don't know. That's not my -- these kind of

4 samples, again, were not collected by myself, and I

5 don't know what the designations are.

6 Q. This is just the way the bottles were labeled

7 when they came to you for analysis?

8 A. That's correct. And these are the results of

9 those analyses.

10 Q. Do you have any idea as to who would know

11 whether they're replicate values?

12 A. There are a series of field notes attached to

13 the back, and the person to ask would have to be

14 whoever collected them for the Refuge, which would

15 either be Su Jewell or whoever else. I assume. I'm

16 assuming these samples were collected by the Refuge.

17 Q. On several other pages of the materials

18 you've turned over to us, there are similar match-ups,

19 8 and 8-B, 14 and 14-B, 19 and 19-B.

20 I can provide those pages to you, if you want

21 to look at them. I think they're in -- actually, 8632

22 is another -- let me just ask you about Bates number

23 8632. There are similar match-ups, under H2O bottle

24 ID, of 5, 5-A, 6, 6-A. Do you know what they are?

25 A. I do not.

489

1 Q. So, you don't know whether they're replicate

2 values, either?

3 A. No, I don't.

4 Q. Dr. Jones, do you have any idea as to where

5 these samples were taken as reflected on the front

6 page, 8626?

7 A. I do not.

8 Q. Again, would that be, in all likelihood, Su

9 Jewell or someone associated with her?

10 A. Refuge staff.

11 Q. Do you have any chain of custody forms or any

12 other records that would reflect such information?

13 A. The samples are turned over by the Refuge to

14 us. They would maintain any kind of -- they would know

15 who handles the samples, in our laboratory. The

16 samples are handled by -- it would be rather silly to

17 have a chain of custody, to say they moved from one

18 room to the next.

19 Q. All you did was analyzed the samples given to

20 you, and that's the extent of it?

21 A. At this time, I have not been asked to make

22 any interpretation of this data.

23 Q. Would that likewise be true about both the

24 sediment and the water sampling for the Loxahatchee

25 Refuge?

490

1 A. Yes.

2 Q. I just wanted to be clear. Just one final

3 question in this regard, just to clarify the point.

4 Concerning all the information that's

5 contained in the Loxahatchee total -- the Loxahatchee

6 data, beginning with Bates number 8626, you didn't

7 collect these samples and don't know where they were

8 taken from. Correct?

9 A. I did not collect the samples.

10 In this file, there are a number of samples

11 that I do know where they were taken from. The samples

12 that have some other non-descript characteristic,

13 especially those that appear to have maybe reference

14 to, perhaps, League entry and access, I don't know

15 where those samples were taken from.

16 This file does contain samples that I do know

17 the location.

18 Q. Could you give me some examples? Would you

19 just identify what these samples are?

20 A. They're rainfall collectors, for instance.

21 Q. Could you identify a particular page?

22 A. The first one would be 8633, DRJ.

23 Q. Okay.

24 A. That has got a series of rainfall collectors

25 on it.

491

1 Q. Are there any other that you know the

2 location of?

3 A. There are additional samples with the same

4 designation, "Rainwater."

5 Q. So, you would know all the rainwater samples?

6 A. Yes. And I assume that some of the other

7 samples, for instance, on DRJ 00008653, that has what

8 would appear to be the 15 stations or 16 stations. I

9 mean, I assume that those numbers are referring to

10 that.

11 So, there are some things that -- I just

12 don't want the statement to be reflected in the record

13 as if I don't recognize any of this data.

14 Q. Let me ask you, then, specifically, about

15 pages 8626 through 8632. That's the first six pages of

16 the document.

17 Do you know the locations of those samples?

18 MS. PONZOLI: It's been asked and answered.

19 A. The first four pages, which have numerical

20 one through four at the bottom, typewritten in,

21 starting with 8626 and going through 8629, represent

22 sediment samples, and as I have answered previously, I

23 don't know what those samples represent.

24 You then went through, I believe, was it

25 through 8631?

492

1 Q. 32.

2 A. Those samples have some consistency with it.

3 It appears that they're water samples, that they may be

4 from the 16 stations. I just don't recognize, as I

5 indicated before, all of the designations. For

6 instance, the Fs, and the A, and the questions that you

7 have asked me, and I've answered before.

8 Q. Let me ask you to turn your attention now to

9 pages 8645 -- 8646.

10 Do you know where these samples were taken?

11 A. Other than, it says, "Loxahatchee," gives me

12 a date, and then it says, "Sawgrass/cattail mix, SG

13 plus W mix, C plus P, canal edge." Those types of

14 things.

15 Other than that, no, I don't know what those

16 would be, without going and asking Refuge staff.

17 MR. HYDE: Let's label the other group of

18 documents which begins with Bates number DRJ

19 00009462, as Exhibit 61.

20 (The documents referred to were thereupon

21 marked Jones Exhibit 61 for Identification.)

22 BY MR. HYDE:

23 Q. I'd like you to turn your attention in this

24 document to DRJ 8620.

25 Beginning on that page is a collection of

493

1 data, which concerns Loxahatchee total phosphorus

2 surface water, and as you go into the next several

3 pages, your sample bottle designation as reflected in

4 this document, goes through 38.

5 Can you explain to me the purpose of that

6 numbering system, if you know?

7 A. Yes. These are the results of my samples

8 collected in the Everglades Agricultural Area, entry

9 and access.

10 MS. PONZOLI: I believe they are already an

11 exhibit in this deposition, Mr. Hyde.

12 BY MR. HYDE:

13 Q. So, you know that the notation at the top of

14 the page, EAA, reflects the fact that it's really your

15 EAA samples?

16 A. These pages are already an exhibit and have

17 been marked, and we've discussed them.

18 Q. Dr. Jones, the record of your notebook, or

19 the copies of your notebook, is none too clear, even on

20 this particular draft, and it appears to be only three

21 pages.

22 Could you just quickly read that into the

23 record, for our benefit?

24 A. Read the notebook?

25 Q. Yes.

494

1 A. The original --

2 MS. PONZOLI: Yes, you can read the original.

3 A. I have enough trouble with my handwriting,

4 let alone when it's in that state.

5 Q. Obviously, just do it line-by-line, if you

6 can.

7 A. I'm sorry. I am not -- I have a bad eye, and

8 I don't read well.

9 Q. That's quite all right. Take your time.

10 A. You will have to excuse me.

11 The first line says, "6/22/93, ENP nutrient

12 dosing site."

13 The second line says, "8:50 a.m., Davis,

14 Qualls, Dennis," I have "Gus," and I'm not sure whether

15 I've got his last name down there. "Almos."

16 A-L-M-O-S.

17 The next thing, entry, is, next line, is

18 "2:15 p.m., L67, in dense cattail area, very atypical

19 of rest of system. Sample number EP-11 H2O two sed."

20 Q. S-E-D?

21 A. S-E-D, period.

22 The next line says, "3:00 p.m. west of EP-1

23 in cattail area. Sample number EP-2." That was a line

24 immediately below that. I'm sorry.

25 The next line is, "4:00 p.m., sawgrass, still

495

1 in impacted area west of EP-2. Sample number EP-3."

2 Those were two lines.

3 There's a blank line now.

4 There's another line that says, "6/23/93,

5 Davis, Qualls, Dennis, Richardson."

6 The next line is, "9:15 a.m., S-332, Taylor

7 Slough, cattail area, south of structure, pumping full,

8 sample EP-4," and that was comprising three lines

9 there.

10 The next line starts, "10:00 a.m.,

11 approximately 75M southwest: Or SW, "of EP-4,

12 Eleocharis."

13 The next line is, "Marsh water only,

14 EP-5-soil is marl and peat mix. Greater than 50

15 percent marl."

16 There's now another line, and it says, "11:00

17 a.m., approximately 500MN of EP-4. Marl and

18 sawgrass - no cattail. Complete cover of periphyton,

19 EP-6."

20 That was three lines there.

21 The next series of lines starts with, "11:30

22 a.m., approximately 1KM south of EP-4. Sagittaria

23 Rhynchospora" -- I'm sorry. That's either Rhynchospora

24 or it might be Rhyzophera, because I believe they were

25 mangroves, and so it could be that.

496

1 "Some sawgrass, periphyton and marl soil,

2 EP-7."

3 That was, again, a series of three lines.

4 The next notation begins, "1:45 p.m., south

5 of EP-7, cattail, marl and bird rookery to south and

6 north. Sample EP-8." Again, that was three lines.

7 The next line begins, "2:30 p.m., W of EP-8,

8 approximately 50M sawgrass, sample EP-9 H2O only." Two

9 lines.

10 The next line, or the next notation, begins,

11 "2:45 p.m., E of EP-8, approximately 200 meters,

12 sawgrass and Rhynchospora." Or it may be "Rhyzophera."

13 "Sample, EP-10, H2O only." And that ends

14 page DRJ 00009281.

15 The next page, DRJ 00009282, begins, "23 June

16 '93, continued.

17 "3:30 p.m., approximately 2KM N of TSB,

18 Eleocharis, marsh - center of slough, sample EP-11."

19 That was two lines there.

20 The next begins, "4:00 p.m., approximately

21 2KM, south of TSB Eleocharis." I believe that's my

22 scrawl for, "Marsh, center of slough, sample EP-12."

23 Two lines.

24 Now the next begins, "5:10 p.m.,

25 approximately 3KM W of U. S. 1 on c-111, sawgrass, red

497

1 mangrove, marl soil, sample EP-13, no soil."

2 Three lines there, now begin with, "5:30

3 p.m., approximately 3KM W of U. S. 1, off C-111, south

4 of EP-13, approximately 3KM, sawgrass, many dwarf reds,

5 marl, soil, H2O only, sample number EP-14." And

6 there's a blank line.

7 We go to "24 June, 1993. Davis, Qualls,

8 Richardson and Birch.

9 "8:55 a.m., approximately 100M S of S-12C,

10 yuck," exclamation point. "Sample number EP-15."

11 That was two lines.

12 "10:05 a.m., approximately, 100M S of first

13 culvert, east of S-12C, number EP-16 only water."

14 The next series of lines, "11:15 a.m.,

15 approximately 700 meters W of S-12C - humongous

16 sawgrass. Number EP-17 H2O only."

17 Then there's a blank line.

18 "25 June, 1993, Davis, Qualls, Richardson,

19 Birch, Jewell and Anderson."

20 Given the legibility of this handwriting, I

21 am assuming that these are notes written by Su Jewell.

22 MS. PONZOLI: If they're notes written by Su

23 Jewell and not your notes, --

24 MR. HYDE: I would still like to have it read

25 into the record, because the copy is still poor.

498

1 MS. PONZOLI: I don't mind, but you need to

2 understand that he is interpreting someone else's

3 handwriting.

4 MR. HYDE: So noted.

5 MS. PONZOLI: If you are going to ask someone

6 else to do that same task, I suggest we wait and

7 have them do it.

8 MR. HYDE: I don't know that we will.

9 MS. PONZOLI: Can we stipulate that's not

10 going to happen?

11 MR. HYDE: No.

12 MS. PONZOLI: I'm asking we not do it twice.

13 MR. HYDE: I don't think it will happen

14 twice.

15 A. Continue. The next line reads, "08:30.

16 Number EP-18. Approximately 6," she has .6, sorry, "M

17 south of 12C center, two grabs and one water. Short,

18 sparse sawgrass." That was two lines.

19 The next line starts, "09:35, number EP-19,

20 site is 100 feet," I believe is that notation. There's

21 a single slash at the right-hand corner of that number.

22 "North of Ron's target, near trees. 1.4 miles south of

23 structure center. Two grabs and one water. Very open,

24 short sawgrass, rich periphyton, bedrock at surface,"

25 and that ends that page.

499

1 We now go to page DRJ 00009283.

2 MS. PONZOLI: Are these continuing in what

3 you believe to be Ms. Jewell's handwriting?

4 THE WITNESS: Yes, they are.

5 A. It appears to be a "10/30, EP-203.3 miles

6 south of last station, EP-19," in parentheses. "In

7 center, two grabs and one water, no target seen here.

8 Very open, sparse, short sawgrass, and Eleocharis, four

9 miles south of 12C."

10 The next lines begin, "11:45," it looks like

11 "EP," I'm assuming it is, "EP-21, 8.0 miles south of

12 S" -- no, I'm sorry, "of 12C, on center, two grabs, one

13 water, sparse, very open sawgrass."

14 That was three lines.

15 The next series -- the next series begins,

16 "14:20, EP-22, lateral one-quarter - one-half mile east

17 of EP-18. One water sample only, no grabs. Medium

18 density sawgrass, some Rhynchospora."

19 There's a blank line, and then we begin with

20 notes that were once again, recorded by myself.

21 The next line begins, "28 June, 1993, Qualls,

22 Davis, Richardson, Dennis."

23 The next entry begins, "08:30, west of EP-21

24 by 2MI, west of NDS in Eleocharis, sample EP-23, H2O

25 only."

500

1 That was three lines.

2 Beginning the next entry is, "10:12, east of

3 EP-21, sawgrass marsh, sample EP 24, H2O only." Two

4 lines.

5 The next entry begins, "11:50, W of," it

6 looks like 4 something L, and I cannot read that at the

7 moment. You would have to -- I'm sorry. I can't make

8 that out.

9 "EP-25. Sawgrass and marl." That was two

10 lines.

11 The next entry begins, "12:55, E of four mile

12 S-T" -- four mile station. That must be mile, M, in

13 the previous line.

14 "Sample EP-26, H2O only." Two lines.

15 Now the next line begins, "2:40 p.m., east of

16 EP-19, one-half MI, Pinnacle Rock, EP-27, H2O only."

17 Two lines, and the next entry begins, "3:45

18 p.m., W of EP-19, EP-28, H2O only."

19 The next line, "4:40 p.m., W of 18, 0.25MI,

20 sample number EP-29, H2O only."

21 Move on to the next page, which is DRJ

22 00009282. It starts with the notation, "23 June '93,

23 continued."

24 The next entry is --

25 Q. Excuse me, Dr. Jones. I think you read DRJ

501

1 9282, and I think you meant 9284.

2 A. I read 9282? Did I -- 9281 -- I'm sorry, it

3 was double-sided. I'm sorry, I flipped the page back

4 over the other way.

5 Q. Okay.

6 A. I was reading from page, the wrong page.

7 I'm now on DRJ 00009284, and the first line

8 of this page reads, "29 June, 1993, Davis, Richardson,

9 Qualls, Dennis."

10 The next entry is, "EP-30, 9:00 a.m., Big

11 Cypress, south of Fill Road, approximately 200 feet,

12 H2O."

13 The next entry is, "9:40 a.m., approximately

14 250 feet west of EP 30, EP-31, H2O only."

15 The next entry, "10:35 a.m., approximately

16 500M east of EP-30, Rhynchospora and some sawgrass.

17 EP-32."

18 The next entry is, "11:25 a.m., approximately

19 200M S of EP-30, Eleocharis and sawgrass, EP-33, H2O

20 only."

21 The next entry is, "1:05 p.m., approximately

22 1KM west of EP-33. Sample EP 34. Eleocharis."

23 Something I don't recognize. Sorry.

24 Then "Sagittaria," it looks like an

25 "EP-20" -- I'm sorry, "H2O only." That's what it is.

502

1 The last entry is, "1:30 p.m., approximately

2 2KM south of EP-30, sawgrass, willow, sample EP-35."

3 That finishes the notebook.

4 Q. Dr. Jones, can I safely presume that when you

5 use the letter M, you mean meters?

6 A. When I use the letter M. I can't attest to

7 what Su Jewell did in her notes, when she used the

8 letter M.

9 MR. HYDE: Thank you, very much.

10 I'm going to turn you over now to Mr. Sams.

11 I appreciate your patience.

12 MR. SAMS: Did that receive an exhibit

13 number?

14 MR. HYDE: We didn't mark it as an exhibit

15 number.

16 MS. PONZOLI: It's previously in the record,

17 Mr. Sams.

18 MR. SAMS: Can we go off the record and take

19 five minutes?

20 MR. HYDE: Fine.

21 (Thereupon, a brief recess was taken,

22 after which the following proceedings

23 were had:)

24 MR. SAMS: Dr. Jones, good morning. My name

25 is Gary Sams. I'm a member of the law firm that

503

1 represents the Sugar Cane Growers Cooperative, and

2 Wedgworth and Roth, who are parties to this

3 proceeding.

4 The first area I would like to ask you some

5 questions about, is in the area of mercury, and

6 I'm going to refer you to certain documents which

7 were produced for us, I believe last week, in

8 response to the notice to produce which we served

9 in this case.

10 The first document appears to be composite

11 documents, a composite exhibit, and I believe it

12 will be number 62.

13 (The document referred to was thereupon

14 marked Jones Exhibit 62 for Identification.)

15 CROSS EXAMINATION

16 BY MR. SAMS:

17 Q. I'd like to ask you to examine it, please.

18 I believe all these were together when we

19 received them.

20 Can you tell me what the documents are here,

21 and whether they cover the same or different subjects?

22 A. First let me state that this document was

23 produced a year ago, not last week.

24 Q. Thank you. With that correction.

25 A. They in all likelihood were produced

504

1 together. This is not the complete contents of the

2 file that this document, or this series of documents,

3 would have been contained in.

4 Q. Is it your statement, however, that they

5 would have been contained in the same file?

6 A. I believe so.

7 Q. Could you identify the document that appears

8 on the first -- as the first page, and is printed in

9 hand?

10 A. I don't recognize the handwriting. I'm not

11 saying it's not in my file. I'm just saying I don't

12 recognize the -- I don't recognize the handwriting.

13 Nor do I recognize this particular document.

14 Q. When you say you don't recognize the

15 handwriting, does that mean you don't -- you can't

16 identify the author?

17 A. That's correct.

18 Q. If we could skip the next page, and go to the

19 third page, could you identify that document for me?

20 A. It's hard to identify it precisely, because

21 the description of the document, I believe, is obscured

22 by what looks like, perhaps, a Post-it or something

23 like that, up in the corner.

24 But I'm assuming that it's a portion of the

25 cooperative agreement between the United States

505

1 Department of Interior, Everglades National Park, and

2 Florida International University.

3 Q. Is this a draft?

4 A. I have no way of knowing whether it's a

5 draft. I can say that it's obviously not the final,

6 signed copy of it, because there are no signatures on

7 the second page.

8 Q. What was the purpose of this cooperative

9 agreement?

10 A. It says, "Master agreement." We had for nine

11 years now, a cooperative agreement between Everglades

12 National Park and Florida International University, for

13 conducting of cooperative research and training.

14 Q. I see in the second "Whereas" clause, the

15 reference to the desire to conduct research on water

16 quality to evaluate the enhanced presence of methylated

17 mercury in the food chain, et cetera.

18 A. I'm sorry. Where are you at?

19 Q. The second "Whereas" clause.

20 A. Okay.

21 Q. Was that the specific purpose of this

22 individual document, to the best of your ability to

23 recall?

24 A. I would assume that -- these are documents

25 that I don't prepare. These are prepared by the

506

1 National Park Service. Their intent, I can't speak to.

2 Q. I believe you said that FIU and the Park

3 Service, or the Park, have had a nine year existing

4 master cooperative agreement. Is that correct?

5 A. We're in the ninth year of that agreement, I

6 believe.

7 Q. So, it would have commenced approximately

8 1985?

9 A. About. It's been renewed. It's been renewed

10 once since then. So, this is the second such agreement

11 that we've entered into with them, with the Park.

12 Q. Did you have a role in developing the

13 agreement?

14 A. The master agreement?

15 Q. Yes.

16 A. The original master agreement, I did not.

17 The second master agreement, I was the principal author

18 for FIU. Well, I was the principal -- after we turned

19 it over to the attorneys and they did their stuff.

20 Q. Did you have a role in developing this

21 particular cooperative agreement?

22 A. Without -- there's an obscured portion of

23 this thing.

24 Q. Perhaps I can cut through that.

25 A. Yes. That leaves me with a problem, because

507

1 we do these things as subagreements, and I'm not

2 familiar whether they're still using the subagreement

3 routine, or whether it's a master agreement, or how

4 they're doing it anymore in the Department of Interior,

5 National Park Service.

6 Q. Would it help you to turn to the last two

7 pages of this composite?

8 A. Master agreement. It has, "Master agreement

9 CA-5280-8-8007."

10 Q. Correct.

11 A. I believe that is -- doesn't have the -- the

12 Post-it note on it. I'm not certain it's the same

13 thing, but -- the first page appears to be the same,

14 but the second page is definitely different, and it

15 would appear that the second page of the first document

16 is the final page of this. So, I mean, they're -- I

17 think they were put together in the wrong order.

18 Q. Let me refer you to the very last page of the

19 composite, and ask you if that appears to be the second

20 page of the cooperative agreement that we've been

21 discussing, which appears to be the third and fourth

22 pages?

23 A. It's very possible, because of the

24 enumeration along the left-hand column, that it fits

25 with the -- with the numbers there.

508

1 Now, that's --

2 Q. Assuming that's correct, does the information

3 on that final page of the composite, help you to

4 identify the subject study?

5 A. Yes, it does.

6 Q. Did you participate in developing that study?

7 A. Yes, I did.

8 Q. Was that study ultimately approved and

9 funded?

10 A. Yes, it was.

11 Q. I note on, again, on the last page of the

12 composite, that the third paragraph identifies certain

13 deliverables and certain dates for interim and final

14 reports.

15 Were there interim and final reports

16 delivered by the dates indicated there?

17 A. In the form of data turned over, yes. The

18 final report -- this is an ongoing project, so it is

19 under continuation.

20 Q. No text? Just data?

21 A. There are -- in the master agreement, which

22 you don't have here, I mean the master cooperative

23 agreement, there are a number of things that say how

24 reports and such -- what they may constitute.

25 Our general mechanism and the agreement we

509

1 have in my particular laboratory, is that we do that in

2 the form of scientific publications, abstracts,

3 presentations and the like.

4 So, we don't -- we do not prepare Everglades

5 National Park reports, if you will, to be bound by the

6 Park Service.

7 So, this agreement has to be taken into

8 context with the master agreement between Florida

9 International University and the National Park Service.

10 Actually, between the State of Florida and the Park

11 Service.

12 Q. If you could continue to refer to the last

13 page of the composite, below the two report dates, it

14 says, "A copy of all reports shall be submitted to

15 Everglades National Park," and names -- identifies the

16 official and address.

17 Were any reports other than data, submitted

18 to the Park?

19 A. Like I said, this is a continuing project,

20 and I do not believe so. In fact, I know there were no

21 reports submitted to the Park.

22 Q. Were data submitted to the Park?

23 A. Data were submitted to Dr. Michael Soukup,

24 and --

25 Q. Were those data provided among the documents

510

1 which were produced for us?

2 A. Yes.

3 Q. Could you recall from memory, the format in

4 which those data were produced for us?

5 A. I mean, values of total mercury in water,

6 values of total and methylmercury in soils and sediment

7 of Everglades National Park, and Water Conservation

8 Area 3A.

9 Q. I'll show you another document, and ask you

10 if those are the data that you are referring to?

11 A. No.

12 Q. Referring you again to the last page of the

13 composite exhibit, paragraph number 2, it appears to

14 provide for payment to FIU in an amount not to exceed

15 $341,871.

16 Is that the dollar amount for which this work

17 was performed?

18 A. This work is under continuation. It has

19 received -- there's additional funds placed into this

20 particular account. Much of the work outlined in this

21 particular cooperative agreement has not been completed

22 for a number of reasons.

23 Q. What are those reasons?

24 A. Predominantly, the need to develop specific

25 analytical methods for working in Everglades soils and

511

1 waters, for mercury analysis.

2 Q. Have those methods been developed?

3 A. We are, at the current time, working on them.

4 Q. When you refer to "we," to whom are you

5 referring?

6 A. My research group at the University,

7 particularly the -- those people associated with the

8 mercury project.

9 Q. Anyone outside the University?

10 A. The people in the Environmental Protection

11 Agency.

12 Q. Who are the principal persons?

13 A. Dr. Jerry Stober.

14 Q. Is there anyone else at EPA, with whom you

15 deal particularly on this issue?

16 A. For mercury?

17 Q. Yes.

18 A. Jerry would be my principal contact. There

19 are people working for Jerry, that I have had times to

20 speak with, but --

21 Q. Have any publications or reports other than

22 to the Park, been generated under this agreement?

23 A. We have submitted two abstracts at this time,

24 one where I'm principal author, and another where, I

25 believe, Jerry Stober is principal author.

512

1 Q. To whom have you submitted the one of which

2 you are the author?

3 A. It's for a conference occurring sometime

4 later this year, and I'm sorry, I don't remember

5 exactly which conference it would be. It's in the

6 documents.

7 Q. Do you know to whom Jerry Stober submitted

8 his abstract?

9 A. To the same group. We were both requested to

10 submit abstracts by Tom Atkeson, who is the State's

11 mercury coordinator.

12 Q. Are those the only publications or written

13 reports that have been generated in connection with

14 this study?

15 A. We have a standard operating procedure, SOP,

16 that, as I indicated the other day, has been produced

17 in the documents, would have been in the file with this

18 mercury material, and then the first draft of this

19 analytical paper that we're working on now, but that

20 has not been sent to the agency.

21 Q. Are there any other reports or written

22 publications that have been produced in connection with

23 this study?

24 A. Not to my knowledge.

25 Q. Would you know if Mr. Stober had produced

513

1 any?

2 A. No, I would not, unless he sent them to me.

3 Q. What is EPA's role in this ongoing study?

4 A. I think I indicated to you that they have

5 supplemented this particular study. It has grown from

6 this initial document, and project, into a much

7 expanded project.

8 This particular effort involved Dr. Tamar

9 Barkay at EPA, and the laboratory in Gulf Breeze.

10 Since that time, I'm no longer cooperating.

11 We're no longer working together on this project.

12 This is not the appropriate document to be

13 using, for me to try to describe what EPA's role is.

14 It's not contained in it.

15 Q. I assume EPA has a role besides funding, but

16 tell me if that's correct or incorrect.

17 A. Yes. They do.

18 Q. What role does Jerry Stober play in

19 connection with the study?

20 A. Dr. Stober, I believe, is the person who is

21 essentially in charge of EPA's interests or aspects of

22 the, if you will, South Florida Mercury Study.

23 Q. Does the Florida Department of Environmental

24 Protection, have a role in connection with this study?

25 A. No, they do not.

514

1 Q. Does the South Florida Water Management

2 District, have any such role?

3 A. No, they do not.

4 I'm sorry. They may be collecting some

5 samples from structures for us to be analyzed in my

6 laboratory.

7 Q. You say they may be. Is that a future

8 possibility?

9 A. I have sent bottles up to the district in

10 November, and they have yet to collect any samples and

11 send them to my laboratory, under this project. So,

12 they may or may not collect them. I don't know if they

13 will.

14 Q. Did the FIU-National Park Service cooperative

15 study that's reflected in Exhibit 62, later evolve into

16 the EPA South Florida Mercury Study?

17 A. No, it didn't.

18 Q. Why are you in doubt about whether the South

19 Florida Water Management District will analyze the

20 samples that you referred to as having sent to them?

21 A. They won't analyze them.

22 Q. What is the doubt that you have about their

23 role?

24 A. I just have not received any samples from

25 them, that they've collected yet, so, you know -- if I

515

1 would have had, you know, a monthly or biweekly set of

2 samples coming from the district, then I would know

3 what their involvement is. That this is an arrangement

4 made by the EPA, not by myself.

5 Q. You referred to analytical methods that are

6 still under development. Without having developed the

7 analytical methods, how were you able to complete the

8 mercury analysis that's reflected in the data that you

9 turned over on production?

10 A. There are a number of different types of

11 mercury analysis. The types of analysis that we made

12 for the production did not involve any of the

13 experimental methods, or they involved methodologies

14 which we had worked out prior to that time, and as I

15 pointed out, those are reflected in our SOP.

16 Q. Within you refer to "they," are you referring

17 both to methods that had been worked out prior to that

18 time, and experimental methods, or only the latter of

19 those two?

20 MS. PONZOLI: Object to form. I think it's

21 confusing. Do you understand?

22 THE WITNESS: I do not understand. I'm

23 sorry.

24 BY MR. SAMS:

25 Q. It's an attempt on my part to elucidate an

516

1 answer that was compounded, not necessarily

2 grammatical.

3 What I'm trying to learn, Dr. Jones, is, with

4 respect to the experimental methods, first of all, were

5 those ones that you relied on in developing the data

6 that you have turned over?

7 A. Some of the data that I've turned over.

8 Q. What are those experimental methods, and if

9 you can give me a general description, the data

10 produced by them?

11 A. The primary experimental method would be the

12 measurements of methyl -- the organic species of

13 mercury in soils and water, development of extraction

14 techniques and things that work for the Everglades

15 system in particular. And the data, to answer the

16 second part of your question, the data would be those

17 reflecting the analysis of organic mercury in sediment,

18 in water. I should say the speciation. I'm sorry.

19 Q. When you refer to "speciation," are you

20 referring to methylated mercury?

21 A. That would be one of the species.

22 Q. Could you identify the others?

23 A. There are a number of organic forms of

24 mercury, and we are able to identify a number of those

25 different forms.

517

1 I can't identify, you know, exactly the --

2 all of the species that we can currently chromatograph.

3 Some of them are not of a scientific interest in the

4 system, so we don't particularly look for them.

5 Q. Could you identify for me, at least those

6 species of mercury which you do intend to analyze in

7 your study?

8 A. I won't give you an exhaustive list, because

9 if we have a compound of unknown composition, we will

10 plan to determine it, using other techniques, what that

11 compound is.

12 Right now those species predominantly

13 represent themselves as monomethylmercury,

14 dimethylmercury, monoethylmercury, diethylmercury,

15 methylethylmercury, phenylmercury, monophenylmercury,

16 biphenylmercury, and the combinations thereof, if you

17 will.

18 I really -- we could go on to a list of

19 probably 20 compounds that we have interest in, and

20 have seen at the moment.

21 Q. I appreciate that. As a non-scientist, it's

22 a bit of torture for me to repeat what you laboriously

23 just stated.

24 I assume that's -- those are the species that

25 you have a present intent to analyze for?

518

1 A. We have a present interest in those species.

2 Q. What is the basis for your interest?

3 A. Those particular species are the species of

4 which we would expect, based on the body of the

5 scientific literature, to represent the range of

6 organic mercury compounds that we might observe in the

7 environment.

8 Q. If I may, I would like to refer you to the

9 document that appears to start on page 6 of the

10 composite, Dr. Jones.

11 A. Is this it?

12 Q. That's it. It's "Environmental parameters

13 effecting," et cetera.

14 A. I have it.

15 Q. First, I would like to refer you actually to

16 the third page of that document. About a third of the

17 way up from the bottom there are -- there appears the

18 statement, "The basic design of the project will be

19 divided into two sections."

20 Do you find that spot in the document, Dr.

21 Jones?

22 A. Yes, I do.

23 Q. Item one below it reads, "Field

24 determinations of mercury content and speciation."

25 When was this document first created, to the

519

1 best of your knowledge?

2 A. In its context here, I'm having difficulty.

3 There are other ways that I could have been presented

4 this particular document, that would let me know

5 exactly that date.

6 The only thing I can do would be to go to the

7 third page of the document -- no, it doesn't have a

8 date on it. I'm sorry. I don't think there's any way

9 for me to --

10 Q. May I refresh your memory or offer you that

11 opportunity, by referring to the last page of the

12 composite?

13 A. Yes. Please do.

14 The only thing I could guess would be the --

15 from the reports --

16 Q. If I could refer you to paragraph 2, it

17 appears that there's an amount proposed for fiscal year

18 1991. Does that help refresh your memory?

19 A. '91 is a possible date. I mean in 1991. But

20 fiscal year monies are not necessarily committed, you

21 know, in October of the year, whatever. I'm assuming

22 it's in that time frame, though. I mean, that would

23 seem reasonable to me.

24 Q. If that does seem reasonable, referring back

25 now to the third page of the environmental parameters

520

1 document, does that mean that since the '91/'92 time

2 frame, you have been working on the development of

3 methods for determining mercury speciation?

4 A. We have been, but that's not necessarily

5 based on the material on the third page of this

6 document, or that's not necessarily the reasoning.

7 Q. When did you start working on the development

8 of methods for mercury speciation?

9 A. After this document was compared -- prepared,

10 because under this circumstance here, we were not

11 planning on doing the speciation of mercury. This was

12 to be done by Mr. Nicolas Bloom, I believe, and with

13 help from the EPA laboratory in Gulf Breeze.

14 They did not develop that capability, to my

15 knowledge. They did not develop that capability, and

16 therefore, we took it on ourselves to develop the

17 capability in the laboratory.

18 Q. I believe you indicated that you were no

19 longer cooperating with the EPA lab at Gulf Breeze.

20 Was that the reason?

21 A. No. Just -- I'm now cooperating or working

22 with the EPA laboratory in Athens, and not with the ERL

23 in Gulf Breeze.

24 Q. I'd like to refer you to the second page of

25 the environmental parameters document.

521

1 At the top of the page, there's an incomplete

2 paragraph. Counting down, eleven lines -- ten, eleven,

3 there begins the statement, near the end of the line,

4 "In fact, marl depositing communities continue to

5 function and should serve to sequester a significant

6 portion of the inorganic mercury they are exposed to."

7 Do you find that statement there?

8 A. Yes, I do.

9 Q. How does that sequestering occur?

10 A. The formation of insoluble or relatively

11 insoluble mercury salts.

12 Q. By "sequestering," you mean what?

13 A. Removing from one component of the community

14 into another, where it is less likely to interact.

15 Q. In somewhat layman's terms, does that mean

16 decreased biological availability of the mercury?

17 A. It could.

18 Q. But not necessarily?

19 A. It could, but not necessarily.

20 Q. Why does it not necessarily mean decreased

21 biological availability?

22 A. It depends on a number of parameters, both

23 biological and physico-chemical parameters of the type

24 of marl deposit or the type of deposit that it's in.

25 Q. Could you indicate in general terms for me,

522

1 the biological parameters that may affect the degree of

2 sequestering?

3 A. Microbial activity associated with the soils

4 or sediments. Perturbation, bioperturbation.

5 Q. What is "bioperturbation"?

6 A. For instance, a burrowing organism, that

7 would disturb the soil by burrowing into it.

8 Q. Do any other principal ones come to mind?

9 A. I'm sure there are others, but at the moment

10 those would seem to be the key features.

11 Q. You also, I believe, mentioned a

12 physico-chemical factors.

13 Could you identify the principal ones of

14 those that might affect the sequestering?

15 A. The morphology of the particles, the -- their

16 surface characteristics, and the associated ionic and

17 chemical interactions that would take place on those

18 surfaces.

19 Q. Has your study examined the effects of those

20 factors, and by that I mean both the biological and

21 physico-chemical, that you've identified, on the

22 sequestering of inorganic mercury in marl soils?

23 A. No.

24 Q. Is that intended as part of that study?

25 A. I would hope so.

523

1 Q. Who would make that decision?

2 A. Myself.

3 Q. What will be the basis for your decision?

4 A. This area of study is a very interesting area

5 of study. It has a large number of researchers working

6 in the mercury problem, in Florida.

7 There are limits to the funding. There are

8 limits to the times and the resources, and it just

9 depend on which of the problems I would find most

10 interesting and appealing to proceed with at the

11 moment.

12 Given enough time, most things will be done

13 by either our laboratory or by other laboratories, and

14 that's sort of the way the thing will work out, but

15 it's sort of an iterative process.

16 Q. When you say it's interesting, are you

17 speaking of that from a perspective of a scientific

18 academician, or are you speaking from a perspective --

19 some other perspective?

20 A. I'm speaking from a multiple -- multiple

21 perspectives. Actually two. As a scientist, I'm

22 interested because it's a very interesting scientific

23 problem.

24 I also am concerned about the environment I

25 live in.

524

1 So, I'm interested in it from the same

2 standpoint that any concerned citizen would be

3 interested in something that may affect our lives.

4 Q. Do you consider it something that is

5 important to study in the South Florida mercury

6 initiative?

7 A. I think it's important. I'm not sure of

8 where that importance lies compared to other problems

9 in the South Florida mercury initiative.

10 Q. What mercury salts are formed in marl, if you

11 know?

12 A. That's a question that I really don't think

13 can be answered.

14 Q. Why can it not be answered?

15 A. It's a -- it doesn't make sense,

16 scientifically. It's not a question that would be

17 answered, or asked, by -- what would be formed depends

18 upon what's there. I mean, you have to give me the

19 list of compounds possibilities, and then I can give

20 you the answer on what salts might be formed.

21 Q. Are you aware of the composition of marl in

22 the Everglades?

23 A. In general, major characteristics.

24 Q. If you would, take those characteristics as

25 the basis for your answer. What mercury salts would

525

1 you expect to be formed?

2 A. In the formation of a marl matrix, with

3 mercury, it would always be serving as just another

4 metal. It would complex, if you will, with -- I don't

5 even know if "complex" is the word I would choose.

6 I'm trying to do this in a manner that both

7 of us can understand when we read the transcript.

8 Q. I appreciate that.

9 A. Mercury is not, obviously, the dominant

10 element in marl. The dominant elements would be things

11 like calcium, magnesium, and then the various anionic

12 components, such as carbonates, sulfates, chlorides,

13 and mercury just would form within that matrix.

14 So, whether we actually have something such

15 as mercuric sulfate forming, or whether it's a

16 combination of calcium, magnesium, mercury, in a

17 sulfate, or carbonate, the list is endless. It's one

18 of those things where you would draw it out and put

19 little Ns or Xs for the numbers of these types of

20 complexes.

21 Q. I think you mentioned Mr. Nick Bloom,

22 earlier.

23 What kind of work does he do in connection

24 with the study?

25 A. None, to my knowledge.

526

1 Q. In 1991, '2 and '3, would he have been

2 capable of speciating mercury?

3 A. I believe so. You know, you would have to

4 ask him. I've only spoken to him on one occasion. Two

5 occasions. I'm sorry.

6 Q. Do you know his reputation in the scientific

7 community for analysis of mercury, and mercury

8 compounds?

9 MS. PONZOLI: I don't think it's the job of

10 my expert to qualify or comment on other experts.

11 I'm not telling him not to answer, but I

12 don't think that's what he's here for, and I

13 certainly don't think we've indicated he's going

14 to be offering that type of testimony.

15 BY MR. SAMS:

16 Q. If you can answer it, I would appreciate it.

17 A. I have no reason to doubt Mr. Bloom's

18 qualifications or -- I have no basis for -- on that,

19 other than just reading his papers and the literature,

20 and two conversations with him on the telephone.

21 Q. How long have you been involved in the

22 scientific analysis of mercury and mercury compounds in

23 waters, soils, sediments and aquatic biota?

24 A. Other than some just very, very rudimentary

25 training that I had at EPA and in my student days,

527

1 some -- just since the initiation of this particular

2 study.

3 Q. Have you published any works concerning

4 mercury in the environment?

5 A. Other than the abstracts, which are under

6 consideration for publication at the moment, and the

7 paper that, as I indicated, we're working on now, no.

8 And those have not been published at the moment.

9 Q. Are you consulted by others for your analysis

10 of mercury problems in the environment?

11 A. Yes.

12 Q. With whom have you consulted?

13 A. I've done some work for the Dade County DERM,

14 whatever, Environmental Resource Management.

15 I do work for EPA.

16 I've done work for -- I should say consulted

17 in the area. I have been and am working with the

18 Department of Environmental Protection in helping them

19 set up their laboratory for mercury analysis.

20 There's a group called Research Institute,

21 RTI, Research Triangle Institute, that have visited my

22 laboratory on a couple of occasions, and have me under

23 contract to help them. I believe that that's an EPA

24 project, though, also. I'm not sure.

25 And I have been requested in consultation at

528

1 the EPA laboratory in Cincinnati.

2 I've done mercury analysis for one of the --

3 I believe it's the DOE, U.S. Department of Energy

4 laboratory, in Arizona. I can't think of it right now.

5 For looking at mercury samples for them.

6 I'm currently, as of -- I'm assuming I'm

7 receiving samples from South Florida Water Management

8 District, tissue samples to be analyzed for mercury.

9 I've analyzed tissue samples for Everglades

10 National Park.

11 I've analyzed some tissue samples for one of

12 the National Wildlife Refuges, or bird sanctuaries, if

13 you will, I don't know which one, in the Keys. Without

14 going back and looking through the files, I can't pick

15 that up.

16 And I've done work for various other people

17 on campus, for doing mercury analysis for them.

18 Q. Which of the items that you have listed, and

19 I'll go back through the list to aid you, have included

20 work concerning mercury analysis for the Everglades?

21 If you could just indicate yes or no, as I come to

22 them, I would appreciate that.

23 A. Sure.

24 Q. Dade County DERM?

25 A. That was Biscayne Bay and the canals in

529

1 Miami.

2 Q. In Miami?

3 A. Along the -- in Dade County. Let's put it

4 that way. I don't believe there were any of those in

5 the, what we would consider, say, the EPA, the

6 Everglades Protection Area.

7 Q. Was the product of any of that work, turned

8 over to us in response to our request for production?

9 A. I doubt it. I don't believe it comes under

10 the -- I don't believe it comes under either of the

11 requests for production.

12 Q. What form did the product take?

13 A. Mercury values. Total mercury values for

14 those water samples.

15 Q. Any mercury speciation values?

16 A. No.

17 Q. When was that done?

18 A. I believe it would have been early last year,

19 but I -- I could be off by half a year.

20 Q. Next you mentioned EPA. What work have you

21 done for them?

22 A. Are we going "Yes" and "No" down this, or --

23 Q. Well, that's good. Yes.

24 A. The answer is, yes. I have done work in

25 Everglades samples for EPA.

530

1 Q. Are those all reflected in the documents

2 you've produced for us?

3 A. Yes, they are.

4 Q. Did that involve total mercury?

5 A. It involves total and speciated mercury.

6 Q. Was the speciated mercury done on samples

7 collected in water?

8 A. It has been, but I believe for this -- for

9 this particular incident that I'm talking about, it was

10 done in soils, or sediments.

11 Q. Based on your response, let me ask, have you

12 also speciated mercury in water for EPA?

13 A. We are in the process of doing that. We have

14 not been requested to analyze any specific samples of

15 water for EPA, at this time.

16 Q. When you say, then, that you are in the

17 process, what do you mean?

18 A. We have analyzed some samples that are of

19 interest to EPA, but they have not requested that we

20 analyze specific samples for them, for speciated

21 mercury.

22 Q. For what reason are those samples of interest

23 to EPA?

24 A. Simply because they show some values of

25 methyl and other species of mercury in water, in the

531

1 area of which they're interested in, in the Everglades.

2 Q. What area is that?

3 A. Lake Okeechobee, Florida Bay.

4 Q. I'm not sure I understood your response.

5 Do you mean Lake Okeechobee and Florida Bay?

6 A. No, I said from Lake Okeechobee to Florida

7 Bay.

8 Q. Were all those data provided to us in the

9 response to our request for production?

10 A. Yes.

11 Q. What other work have you done for EPA, if

12 any, speciating mercury?

13 A. Other than in the development of the

14 technique, none.

15 Q. So, I take it you have not done any

16 speciating -- strike that.

17 Where is the DEP lab that you helped set up

18 for mercury analysis?

19 A. I think you added a little more to it than I.

20 I didn't say I helped them set up. I said they're

21 consulting me in the setup of their laboratory in

22 Tallahassee.

23 Q. What'S the status of that project?

24 A. I have a meeting with, I believe it's Mr.

25 Fitzpatrick, next Monday -- no, I'm sorry, the Monday

532

1 following -- to discuss that, and I will know at that

2 time what the status is.

3 Q. Do you know their time frame?

4 A. Their time frame has changed a lot. I

5 believe they were intending to be up and running by

6 now, and I do not believe that that's the case, but, as

7 I said, my next meeting with them is in two weeks.

8 Q. Do you know why they are not up and running?

9 A. No. I have no idea.

10 Q. I would like to show you a document that I

11 believe I showed you before, and ask, if we may jump

12 back one agency on the list, if that is the speciation

13 data for mercury that you provided EPA?

14 A. No.

15 Q. What has been the nature of your consultation

16 with RTI?

17 A. They sent -- on the telephone, we've had

18 several -- I've had several conversations with them,

19 and then, they sent one of their people down to observe

20 my laboratory, and subsequently, requested to put me on

21 a consulting contract for additional development of

22 methodologies and work dealing with clean lab

23 protocols, sampling protocols and analytical protocols,

24 in the mercury analysis.

25 Q. Is that an interlab effort, by which multiple

533

1 labs would be involved?

2 A. I don't know what RTI is doing in that

3 aspect. I just know that they're interested in -- that

4 they're under contract from EPA, to do something, and

5 I'm assuming it has to do with development of mercury

6 methods for EPA, but you would have to speak to the

7 people at RTI, or EPA.

8 Q. As to the last two we've been discussing, DEP

9 and RTI, I take it that, but correct me if I'm wrong,

10 that neither has involved the development on your part

11 of data concerning mercury in the Everglades?

12 A. Neither of those have involved data

13 production. That's correct.

14 Q. What about your consultation with the EPA lab

15 in Cincinnati? Does it involve data production for the

16 Everglades?

17 A. There were some data produced by our

18 laboratory, and the laboratory in Cincinnati, with

19 Everglades -- samples collected in the Everglades.

20 Q. Were there other labs involved in that

21 effort?

22 A. Yes, there were.

23 Q. What were they?

24 A. The laboratory in Athens, Georgia, EPA, in

25 the RSD, and Battelle Pacific Northwest Laboratory.

534

1 Q. Were the results of that work as it relates

2 to the Everglades, provided to us in response to our

3 notice to produce?

4 A. That work was provided to you. The results

5 were.

6 Q. What's the nature of your work with the

7 Department of Energy lab in Arizona?

8 A. They sent me a number of samples collected

9 from volcanos around the world, to analyze for mercury.

10 Q. Was there any involvement of data from the

11 Everglades?

12 A. There's no active volcanos in the Everglades,

13 or inactive, for that matter.

14 Q. Was the work for either the DOE lab in

15 Arizona, or the consultation with the EPA lab in

16 Cincinnati and others, involved with the speciation of

17 mercury?

18 A. At present, no.

19 Q. Is such work intended?

20 A. The possibility exists.

21 Q. I take it that that work is -- such work has

22 not formally commenced. Is that correct?

23 A. That's correct.

24 Q. Then you mentioned work with South Florida

25 Water Management District, and I believe you said

535

1 tissue samples to be analyzed.

2 A. Yes. I received notice last week that they

3 would be sending me the tissue samples of -- that were

4 collected on the League's access to, or the Co-op's

5 access, I don't know whose access, anymore, to the ENR

6 and various other areas, in that EPA.

7 Q. When will they be sending you those tissue

8 samples?

9 A. I don't know that they've all been collected

10 yet. I'm not aware of the status on that. I would

11 assume that it would be within the next few weeks. But

12 that's a guess. I'm just guessing.

13 Q. Are those tissue samples ones that have

14 already been collected, to the best of your knowledge?

15 A. I think I just said that I -- I believe that

16 there are some -- that I don't know the status of the

17 collection.

18 I know that there are some samples that have

19 been collected. I don't know whether there are

20 additional samples to be collected. I have received

21 nothing in my laboratory. So, without seeing a chain

22 of custody, I don't know the status.

23 Q. Will that work involve total mercury or

24 speciation?

25 A. It would be total mercury.

536

1 Q. I believe you also indicated that you have

2 done some mercury analysis for Everglades National

3 Park. Presumably, that was on the -- or concerning,

4 the Everglades. Is that correct?

5 A. Yes.

6 Q. Was that limited to tissue samples?

7 A. I believe it was. I've done -- the majority

8 of my work has taken place within Everglades National

9 Park. So, you know, there are other things that I'm

10 not considering under these -- these are side issues.

11 They're side projects that you've asked me

12 about.

13 So, I'm analyzing soils under the main

14 program, but I believe these were all tissues that I'm

15 speaking of here.

16 Q. Have those results been produced for us?

17 A. I do not believe so.

18 Q. Why were they not produced?

19 A. They were from bald eagles and white-tailed

20 deer, blood samples, and I did them as a service to

21 Everglades National Park, turned the data over to them,

22 and I did not maintain copies of that in my files, nor

23 would it be, I think, responsive to the request.

24 Q. To whom did you turn it over at the Park?

25 A. I know that one set went to, is it Sonny

537

1 Bass, at the Park, and another set of samples was done

2 for -- he was the curator in the museum. And I don't

3 remember his name right now. Somehow, Anderson seems

4 to stick in my mind, but I could be incorrect in that.

5 Q. When did you analyze those samples,

6 approximately?

7 A. I would say around two years ago, but again,

8 that's very approximate.

9 Q. Do you know what the purpose of acquiring

10 your analysis was for the Park?

11 A. No, I don't.

12 Q. Did you do it under a contract?

13 A. Oh, no. I believe I just said I did it as a

14 favor or as a service, to them.

15 Q. Who is Sonny Bass?

16 A. Somebody who works at the Park.

17 Q. Do you know what role that individual plays?

18 A. I've met Sonny on occasion, meaning that he's

19 been in the lunchroom the same time that I've been

20 there, but I don't have a lot of interaction with him.

21 So, I don't know what his role is in the Park. I

22 assume he has something to do with wildlife.

23 Q. You indicated that you had also done analysis

24 of samples collected at a National Wildlife Refuge or

25 bird sanctuary, in the Keys.

538

1 When was that work done?

2 A. Late last year.

3 Q. To whom was it provided?

4 A. I don't know. These were samples that

5 were -- a technician received a telephone call. He was

6 a little more generous than I would have been, and

7 volunteered to do some analysis for them for free, and

8 we did the analysis, sent them the results, and that

9 was the end of it.

10 Q. Did you keep a record of those results?

11 A. I don't have a formal piece of paper record

12 on there. There may be, depending on how long ago they

13 were done, they still may be on the -- on the analysis

14 system in the files.

15 Q. Is the name of the person for whom that work

16 was done as a favor, by the technician, unknown to you?

17 A. Yes, it is. It may have been told to me at

18 one time, but it wasn't something that I committed to

19 memory.

20 Q. I think you then finally mentioned a category

21 of others on the FIU campus.

22 Did any of that work include the analysis of

23 mercury associated with the Everglades?

24 A. No.

25 Q. Can you generalize for me about where -- let

539

1 me back up.

2 Can you generalize for me based on your work

3 for EPA, in which you have speciated mercury, where

4 water methylmercury samples are the highest, and I

5 would like to ask you, if you could, to focus on the

6 basic geographical categories of Lake Okeechobee, Water

7 Conservation Areas, Everglades National Park and

8 Florida Bay.

9 A. Based on the data I produced?

10 Q. Yes.

11 A. My data?

12 Q. Yes.

13 A. I can't.

14 Q. Did you provide for us the data on Lake

15 Okeechobee that you did for EPA?

16 A. I didn't do any work for EPA on Lake

17 Okeechobee.

18 Q. I believe you indicated that you had

19 speciated mercury in soils, and water, from Lake

20 Okeechobee to Florida Bay.

21 Did I recall correctly, your prior statement?

22 A. I believe you're incorrectly characterizing

23 what I said.

24 I believe the interest that EPA has was from

25 Lake Okeechobee to Florida Bay. The samples that I've

540

1 analyzed have not necessarily been from Lake Okeechobee

2 or from Florida Bay.

3 Q. Where have the samples that you've analyzed

4 been from?

5 A. Analyzed for?

6 Q. For EPA.

7 A. Analyzed for --

8 Q. For mercury.

9 A. What form --

10 Q. Methylmercury.

11 A. Water Conservation Area 3A, and the canal

12 sampling locations. This would be for the sediment.

13 Q. Is it sediment in both cases, Water

14 Conservation Area 3A and the canals?

15 A. I've done sediment in both cases.

16 Q. For --

17 A. Canal sediment, in sediment, or soil from the

18 Water Conservation Area.

19 Q. What column --

20 A. In Water Conservation Area 3A.

21 Q. Fish tissue?

22 A. Those would have been in the canal stations

23 throughout the whole system.

24 Q. When you refer to the whole system, to what

25 are you referring?

541

1 A. The area from Lake Okeechobee to Florida Bay,

2 and we have done some additional work in -- with fish

3 collected in Everglades National Park.

4 Q. Were all those data produced for us?

5 A. Yes, they were.

6 Q. The mystery document appears again. Are

7 these those data?

8 MS. PONZOLI: You refuse to ask him what it

9 is?

10 A. I wish you would do that. No.

11 Q. With prompting, I will now puncture the

12 suspense, and ask, what are these data that I've been

13 showing you?

14 A. These are -- I'm going to take just a moment

15 to go through the document.

16 MR. NIEGO: Have we identified it on the

17 record?

18 MS. PONZOLI: No. We keep handing it to him.

19 MR. SAMS: I'll mark it if he can identify

20 it.

21 (Pause.)

22 A. I can identify it. These are results

23 produced by Pacific -- Battelle Pacific Northwest

24 Laboratory, of water, methylmercury content, and soil

25 methylmercury analyses performed by them on the 50

542

1 canal stations surveyed that was conducted by EPA and

2 our laboratory.

3 MR. SAMS: I'd like to have this document

4 marked as Exhibit No. 63, I believe.

5 (The document referred to was thereupon

6 marked Jones Exhibit 63 for Identification.)

7 BY MR. SAMS:

8 Q. Dr. Jones, now, with respect to the document

9 that's been marked as Exhibit 63, do you have a map

10 showing the 50 canal stations at which these data were

11 collected?

12 A. Yes, I do.

13 Q. Was that furnished in response to discovery?

14 A. Yes, it was.

15 Q. Is it part of some other document?

16 A. I haven't seen it in anything that's been

17 produced as exhibits thus far. It would have been in

18 the -- it would not have been in the file containing

19 this information.

20 This information was produced in the material

21 that you received, was it last week? Maybe -- yes.

22 Yes. It would have been in a document produced

23 earlier.

24 Q. Earlier than last week?

25 A. Yes. Meaning in -- in January or whenever my

543

1 documents were taken the first time.

2 MR. GREEN: For the record, we can't find it.

3 MR. SAMS: Off the record.

4 (Discussion off the record.)

5 (Thereupon, a brief recess was taken,

6 after which the following proceedings

7 were had:)

8 BY MR. SAMS:

9 Q. Could you describe with specificity, on the

10 record, Dr. Jones, the map that would show the

11 coordinates of the locations from which the data in

12 Exhibit No. 63 were taken?

13 A. We use a different designation for the

14 samples in our laboratory, but they do have

15 similarities to the column labeled "Sponsor ID," and

16 that -- if you look at that, you would find that there

17 is a series of samples, basically ranging between one

18 and fifty, with some other numbers representing samples

19 that were taken at the top, the surface table samples

20 that were taken at the bottom of the water column, and

21 replicate samples. But that's basically in the sponsor

22 ID.

23 So, the document in question would be a

24 document that would not have, necessarily, the sponsor

25 ID on it, but would have those dots, and then have

544

1 individual numbers, one through fifty, associated with

2 each one of those -- each one of those dots, along with

3 an additional document attached to it that has numbers

4 one through fifty, with latitude and longitude

5 expressed.

6 Q. Now, could you describe what document would

7 be required to translate the information from the map

8 and from the attached document that you just described,

9 to the data as organized in your Exhibit -- your

10 deposition Exhibit No. 63?

11 A. That would require a document that has a

12 listing of the sponsor ID along with our designations

13 of one through 50 replicate and top -- surface or

14 bottom sample.

15 That document -- actually, I shouldn't call

16 it a document, because it doesn't exist. I would have

17 to produce a document as such. In other words, our

18 designations were given to these samples at the time,

19 on the bottles. We labeled the bottles in a different

20 manner than EPA did.

21 Q. Do I correctly understand you to say that it

22 would be necessary to look at the bottles themselves?

23 A. Oh, no. No. I'm saying that for you to do

24 it, you would require the production of a document that

25 has a cross-reference between these things. It could

545

1 be done. It just has not been produced, because it's

2 not necessary for my analysis in the laboratory.

3 MR. SAMS: Dr. Jones, I'm going to show you a

4 document that we will label Exhibit No. 64.

5 (The document referred to was thereupon

6 marked Jones Exhibit 64 for Identification.)

7 BY MR. SAMS:

8 Q. I would ask you to turn to the back of that

9 document, to what is labeled, "Appendix C," but bears

10 various page numbers, A, dash, followed by a number,

11 and in one case, no such number, and ask if that

12 document, or those pages, rather, reflect coordinates

13 for the 50 sampling locations that we have been

14 discussing?

15 A. In Appendix C, labeled from page A-1 through

16 A-39?

17 Q. Through the end of the document, yes.

18 A. No, they don't.

19 Q. What do those numbers represent, if you know?

20 A. They represent the first cycle or the cycle

21 0, for the EMAP grid land, if you will, stations that

22 we will be occupying, not the canal stations.

23 Q. When you say that, "we will be occupying,"

24 first, who are "we"?

25 A. The Environmental Protection Agency and my --

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1 the group that the Environmental Protection Agency

2 sends down for the purpose of sampling, and people from

3 my laboratory.

4 Q. What will take place at these locations?

5 A. We will collect water, if available, fish, if

6 available, periphyton and soil cores at these

7 locations, along with other -- making other

8 measurements on site, and then analyze those primarily

9 for mercury, phosphorus, bug density, things like that.

10 I think those parameters are listed in this document.

11 Q. Would the mercury analysis be speciated?

12 A. We have every intention of doing speciation

13 on these mercury analyses. Whether we do that on every

14 analysis or whether we do it on a subset, has yet to be

15 determined.

16 Q. When is that work planned to be accomplished,

17 if you know?

18 A. The initial round of some of this was

19 scheduled for this week. It got precluded by these

20 proceedings.

21 I don't know when rescheduling is taking

22 place. I would think sometime this summer.

23 Q. Can you tell me whether the pages beginning

24 A-1 and going to the end, which I will assert would

25 appear on their face to skip certain page numbers and

547

1 skip around, represent the order of those pages in your

2 file? Can you tell?

3 A. This document, if I'm not mistaken, is

4 labeled "Draft," and I can't tell without looking, but

5 I'm very certain that a document of this exact type of

6 nature, whether it's this particular draft or not, was

7 presented in a blue, dark blue, plastic binding which

8 was removed upon Xeroxing.

9 The entire document was produced. Whether

10 all pages were Xeroxed and -- in other words, whether

11 this is the complete document, I don't know without

12 going back to the original document and making that

13 comparison. It would appear that pages are missing, or

14 that this is not the most recent version of that

15 document.

16 I see, for instance -- which would not have

17 been in the final version of this document.

18 Q. Have any of your mercury related data been

19 withheld from production based on a claim of privilege?

20 A. No. There are still data that are in the

21 process of being produced, samples that are still being

22 analyzed in the laboratory, and as soon as those

23 samples are available, I'm assuming that we will

24 produce them, if necessary.

25 Q. How many final EMAP stations will be sampled

548

1 and analyzed for mercury as you understand the plan of

2 the study?

3 A. I would have to go to the document and pull

4 out that number. It's --

5 Q. Could you give me an order of magnitude?

6 A. In the hundreds, I believe. I don't believe

7 it goes into the thousands, but it could very well

8 approach a thousand.

9 Q. What precisely do you expect your work to be

10 in that regard?

11 A. Analysis of, at the moment, soils for methyl

12 and speciated mercury. Analysis of fish, tissues, for

13 methylated mercury. I'm sorry, not methylated mercury.

14 I'm sorry. Total mercury.

15 Analysis of water, in all likelihood, for

16 total mercury. We may end up doing the speciated

17 mercury on the waters, also. And then the measurement

18 of a number of other sort of characterizing parameters,

19 such as phosphorus levels and EH pH, those types of

20 things in the field.

21 Q. Could you give me as complete a list of those

22 types of things as you can?

23 A. There is a complete list in this document,

24 and in the later version of this document, and I really

25 hesitate to go down and list all of those off, unless

549

1 you will allow me to stipulate to the fact that I may

2 include some that we're not measuring, and I may

3 exclude some that I just can't remember.

4 Q. Based on your testimony, the documents will

5 speak for themselves. But it is your testimony that's

6 the complete list?

7 A. In the documents, yes.

8 But if something between now and when we

9 actually make the sampling would arise that would be of

10 interest, we may very well add that parameter, but I

11 cannot think of anything at this moment.

12 Q. Why is there doubt about whether you will

13 analyze water column samples for speciated mercury

14 forms?

15 A. We were expecting other laboratories to be

16 able to analyze Everglades samples with the same

17 ability that they've demonstrated for samples collected

18 elsewhere in the United States, and it turned out that

19 these laboratories were not able to analyze Everglades

20 samples.

21 So, we are having to -- the EPA is having to

22 rely upon our laboratory more heavily than was

23 initially planned on.

24 We were not planning on analyzing the water.

25 We were planning on sending that out to another

550

1 laboratory for analysis. That laboratory has

2 demonstrated that they have difficulty with analyzing --

3 I'm sorry, we were planning on sending the soils out to

4 another laboratory.

5 That laboratory has demonstrated difficulty

6 in analyzing the soils. We have that capability.

7 So, this meant that there would be two

8 aspects that we were measuring, water and soil, and we

9 may not be able to do that volume of work in the

10 laboratory.

11 Q. Just to make sure I understood your answer,

12 which was fairly long, in an effort to inform me, no

13 doubt, I think what I understood you to say is that in

14 taking on more than anticipated soil mercury speciation

15 work, due to workload considerations, you may have to

16 not do the water speciation work.

17 Is this a short form, fair summary of what

18 you said?

19 A. We may take on the soils because we have

20 demonstrated our ability to analyze the soils for

21 speciated mercury, and allow another laboratory, which

22 has already demonstrated its ability to do the waters,

23 do the water. In other words, split the tasks up. It

24 will not be that speciated mercury will not be measured

25 in the water. It's just that it will not necessarily

551

1 be done in our laboratory.

2 Q. Has your laboratory been certified for the

3 speciation of mercury in water?

4 A. At these concentrations, there is no such

5 thing as certification for mercury analysis, at these

6 levels.

7 Q. Has your laboratory been found satisfactory

8 for that purpose by those in charge of the EMAP study?

9 A. The EPA has considered our laboratory to be

10 equal to if not superior to the other laboratories that

11 they're using.

12 Q. Is that documented somewhere?

13 A. No.

14 Q. What is the lab that was found to be

15 unsatisfactory for soil mercury speciation?

16 A. I didn't say unsatisfactory. I believe they

17 don't have the detection limits at the moment for using

18 the Everglades soils, and that would be the Battelle

19 Pacific Northwest.

20 Q. What is their detection limit for speciating

21 mercury in soils?

22 A. You would have to ask them.

23 Q. What is yours?

24 A. All I can say is that it's low enough that we

25 can detect -- we can detect methylmercury in the

552

1 majority of the samples, that's greater than the noise

2 of the technique. I don't have the exact numbers

3 available. It also depends upon the individual sample.

4 I believe it's somewhere around .2 or .02 picograms per

5 gram of soil.

6 Q. Do you have a way to convert that for me to

7 parts per trillion?

8 A. It would only serve to confuse everyone,

9 using the terminology of parts per million and parts

10 per billion in soil. Because then the result is that

11 people want to make that comparison to water, and

12 they're not intercomparable in that way.

13 The regular terminology would be to express

14 it as -- in a weight per weight type of a context. At

15 least that would be my type of a thing.

16 I could explain to you how that would be

17 done, but I couldn't tell you exactly what the numbers

18 are to make that conversion.

19 Q. What is your detection limit for the

20 speciation of mercury in the water column?

21 A. I can't recall offhand.

22 Q. Is it less than one part per trillion?

23 A. Oh, certainly.

24 Q. Referring you back, if I may, to what was

25 previously discussed as Exhibit No. 63, which I believe

553

1 you said was the results of analysis performed by

2 Battelle, do you know whether the methylmercury numbers

3 are above or below the level of detection for that lab?

4 A. The designation of U next to those numbers

5 indicates that the numbers were below their level of

6 detection, and they have -- they're uncertain at that

7 point. I don't know what their detection level is.

8 The U just indicates that.

9 Q. Would the level of detection of your lab, be

10 sufficient to detect mercury in those concentrations?

11 A. Which form?

12 Q. The ones marked U?

13 A. Which form of mercury?

14 Q. Methylmercury.

15 A. Depending upon the sample volume we use, yes.

16 Q. Can you tell me why, in the column, "Total

17 mercury," while we're on this document, the initials

18 NA, not applicable, as per the code, appear numerous

19 times?

20 A. They were asked -- Battelle was only asked to

21 analyze a select number of samples, just to make a

22 comparison with analysis from our laboratory. They

23 were not asked to analyze all samples. They were only

24 asked for total mercury. They were only asked to

25 analyze a few of those. Everything else would be

554

1 listed as NA.

2 Q. Who was it that determined what to ask them?

3 A. EPA.

4 Q. Dr. Stober?

5 A. I am assuming.

6 Q. But you don't know that?

7 A. I don't know that.

8 Q. Do you know whether these are the analyses

9 based upon which it was determined that their detection

10 level was insufficient to analyze speciated mercury for

11 the EMAP study?

12 A. They were the set of samples that indicated

13 that they were unable to analyze the 50 canal stations

14 that we monitored. Battelle is currently examining

15 their methods, seeing if they can boost their

16 sensitivity, if you will, or use larger sample sizes,

17 so that to bring their method into a range at which it

18 would work for the Everglades samples.

19 Q. Did your lab do split samples analyses of

20 these done by Battelle?

21 A. Which of them?

22 Q. Methylmercury.

23 A. For the water?

24 Q. Yes.

25 A. No.